Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy=2,2′-bipyridine)

被引：39

作者：

Bayler, A

Canty, AJ ^{[1
]}

Ryan, JH

Skelton, BW

White, AH

机构：

[1] Univ Tasmania, Sch Chem, Hobart, Tas 7001, Australia

[2] Univ Tasmania, Sch Appl Sci, Launceston, Tas 7250, Australia

[3] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 11期

基金：

澳大利亚研究理事会;

关键词：

organopalladium(IV); organoplatinum(IV); iodonium; exchange reactions;

D O I：

10.1016/S1387-7003(00)00144-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of aryl transfer to palladium(II) with concomitant oxidation to palladium(IV) is reported, utilising the reaction of PdMe2(bpy) (bpy = 2,2'-bipyridine) with [IPh2][O3SCF3], together with studies of an analogous platinum system and a structural analysis of trans-PtIMe2Ph(bpy) (bpy = 2,2'-bipyridine). (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：575 / 578

页数：4

共 18 条

[1] SYNTHESIS, REACTIVITY, AND STRUCTURAL STUDIES IN TRIMETHYLPALLADIUM(IV) CHEMISTRY, INCLUDING PDIME3(BPY) AND [PDME3((PZ)3CH)]+, [PTME3((PZ)3CH]+
BYERS, PK
CANTY, AJ
SKELTON, BW
WHITE, AH
[J]. ORGANOMETALLICS, 1990, 9 (03) : 826 - 832
[2] Organoplatinum(IV) and palladium(IV) complexes containing intramolecular coordination systems based on the 8-methylquinolinyl group (mq), including structures of the cation [Pt(mq)Me2(pby)]+ (pby=2,2′-bipyridine) and the palladium(IV) complexes Pd(mq)MeR{(pz)2BH2} (R = Me, Ph;: [(pz)2BH2]- = bis(pyrazol-1-yl)borate)
Canty, AJ
Hoare, JL
Patel, J
Pfeffer, M
Skelton, BW
White, AH
[J]. ORGANOMETALLICS, 1999, 18 (14) : 2660 - 2667
[3] Oxidation of diorganopalladium(II) complexes by water and halogens: Reactions involving methyl group transfer and structural studies of hydrogen-bonded adducts formed by aryl alcohols with the pallada(IV)cyclopentane complex Pd(CH2CH2CH2CH2)(OH){(pz)(3)BH}([(pz)(3)BH](-)=tris(pyrazol-1-yl)borate)
Canty, AJ
Jin, H
Roberts, AS
Skelton, BW
White, AH
[J]. ORGANOMETALLICS, 1996, 15 (26) : 5713 - 5722
[4] CANTY AJ, 2001, IN PRESS HDB ORGANOP
[5] A complex catalytic cycle leading to a regioselective synthesis of o,o'-disubstituted vinylarenes
Catellani, M
Frignani, F
Rangoni, A
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2): : 119 - 122
[6] FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB
DE MEIJERE, A
MEYER, FE
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) : 2379 - 2411
[7] A η2-triflate (OTf) intermediate in the solution dynamics of PtMe3(OTf)•TMEDA:: the 'windscreen-wiper process' revisited
Gschwind, RM
Schlecht, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11): : 1891 - 1895
[8] Palladacycles: Efficient new catalysts for the Heck vinylation of aryl halides
Herrmann, WA
Brossmer, C
Reisinger, CP
Riermeier, TH
Ofele, K
Beller, M
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) : 1357 - 1364
[9] Electrophilic platinum complexes: Methyl transfer reactions and catalytic reductive elimination of ethane from a tetramethylplatinum(IV) complex
Hill, GS
Yap, GPA
Puddephatt, RJ
[J]. ORGANOMETALLICS, 1999, 18 (08) : 1408 - 1418
[10] SELECTIVITY IN REACTIONS OF ALKYL-ARYL-TRANSITION-METAL COMPLEXES WITH ELECTROPHILES
JAWAD, JK
PUDDEPHATT, RJ
STALTERI, MA
[J]. INORGANIC CHEMISTRY, 1982, 21 (01) : 332 - 337

← 1 2 →