Copper-Catalyzed Direct Alkynylation of Electron-Deficient Polyfluoroarenes with Terminal Alkynes Using O2 as an Oxidant

被引：231

作者：

Wei, Ye ^{[1
]}

Zhao, Huaiqing ^{[1
]}

Kan, Jian ^{[1
]}

Su, Weiping ^{[1
]}

Hong, Maochun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 08期

关键词：

C-H BOND; GACL3-CATALYZED ORTHO-ETHYNYLATION; INTERMOLECULAR DIRECT ARYLATION; REDUCTIVE ELIMINATION; COUPLING REACTIONS; ROOM-TEMPERATURE; FUNCTIONALIZATION; ALKENYLATION; ACTIVATION; CARBON;

D O I：

10.1021/ja910461e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A copper-catalyzed direct alkynylation of electron-deficient polyfluoroarenes with a wide range of terminal alkynes is realized for the first time. The reaction proceeds under mild conditions with O-2 as an oxidant.

引用

页码：2522 / +

页数：3

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