Study of removal effect of bisphenol A and β-estradiol by porous carbon

被引:80
作者
Asada, T
Oikawa, K
Kawata, K
Ishihara, S
Iyobe, T
Yamada, A
机构
[1] Niigata Univ Pharm & Appl Life Scu, Fac Appl Life Sci, Dept Environm & Safety Sci, Niigata 9560841, Japan
[2] Nagaoka Univ Technol, Nagaoka, Niigata 9402188, Japan
[3] Kyoto Univ, Kyoto 6170824, Japan
关键词
porous carbon; endocrine disrupting chemical; bisphenol A; beta-estradiol; carbonization temperature;
D O I
10.1248/jhs.50.588
中图分类号
R99 [毒物学(毒理学)];
学科分类号
100405 ;
摘要
The adsorption properties of bisphenol A (BPA), suspected as endocrine disrupting chemicals (EDCs), and beta-estradiol (E2) were examined in this study. Based oil the adsorption isotherm results, the adsorption amount of BPA increased as the carbonization temperature increased. The adsorption effect of a porous carbon carbonized at 400degreesC was minimal, while the adsorption effect of a porous carbon carbonized at 1000degreesC was significant. Although the adsorption effect of the activated carbon was also significant, that of activated carbon was lower than that of the 1000 degreesC porous carbon in the low concentration range, while that of the activated carbon was higher than that of the 1000 degreesC porous carbon in the high concentration range. The adsorption amount of E2 increased as the carbonization temperature increased. The adsorption effect of the activated carbon was midway between 700 and 1000 degreesC. Porous carbon carbonized at 1000 degreesC with a low surface polarity was more effective for the removal of EDCs from environmental water than activated carbon with a large pore volume. It is expected that the 1000 degreesC porous carbon can be used with activated carbon, which has already been used in waste water treatment, in purification plants, etc.
引用
收藏
页码:588 / 593
页数:6
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