Remarkable activity, selectivity and stability of polymer-supported Pt catalysts in room temperature, solvent-less, alkene hydrosilylations

被引：31

作者：

Drake, R

Dunn, R

Sherrington, DC ^{[1
]}

Thomson, SJ

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Dow Corning Corp, Barry CF63 2YL, S Glam, Wales

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 19期

关键词：

D O I：

10.1039/b005912i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polystyrene-resin supported Pt catalyst displays higher conversion, remarkably improved selectivity and excellent recyclability relative to Speier's catalyst in the room temperature solvent-less hydrosilylation of oct-1-ene using trichlorosilane.

引用

页码：1931 / 1932

页数：2

共 9 条

[1]

HARTLEY FR, 1985, SUPPORTED METAL COMP, P204

[2] Poly(siloxane)-supported decacarbonyldimanganese(0) catalyst for terminal olefin hydrosilylation reactions: the effect of the support on the catalyst selectivity, activity and stability [J].

Hilal, HS ;

Suleiman, MA ;

Jondi, WJ ;

Khalaf, S ;

Masoud, MM .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 144 (01) :47-59

[3] Reversibly collapsible macroporous poly(styrene-divinylbenzene) resins [J].

Howdle, SM ;

Jerábek, K ;

Leocorbo, V ;

Marr, PC ;

Sherrington, DC .

POLYMER, 2000, 41 (19) :7273-7277

[4]

Marciniec B., 1992, COMPREHENSIVE HDB HY, P8, DOI 10.1016/B978-0-08-040272-7.50007-7

[5] SELECTIVITY OF POLYAMIDE-SUPPORTED RHODIUM CATALYSTS IN THE ADDITION OF HYDROSILANES TO VINYL COMPOUNDS [J].

MICHALSKA, ZM ;

OSTASZEWSKI, B ;

STRZELEC, K ;

KWIATKOWSKI, R ;

WLOCHOWICZ, A .

REACTIVE POLYMERS, 1994, 23 (2-3) :85-93

[6] Hydrosilylation of phenylacetylene catalyzed by metal complex catalysts supported on polyamides containing a pyridine moiety [J].

Michalska, ZM ;

Strzelec, K ;

Sobczak, JW .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 156 (1-2) :91-102

[7] SELECTIVE ADDITION OF HYDROSILANES TO 1,3-DIENES CATALYZED BY POLYAMIDE-SUPPORTED METAL-COMPLEX CATALYSTS [J].

MICHALSKA, ZM ;

OSTASZEWSKI, B ;

STRZELEC, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 496 (01) :19-26

[8] THE ADDITION OF SILICON HYDRIDES TO OLEFINIC DOUBLE BONDS .2. THE USE OF GROUP-VIII METAL CATALYSTS [J].

SPEIER, JL ;

WEBSTER, JA ;

BARNES, GH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (04) :974-979

[9] Improved synthesis of ion-exchange resins through copolymerization of ligand-modified monomers [J].

vanBerkel, PM ;

Sherrington, DC .

POLYMER, 1996, 37 (08) :1431-1435

← 1 →