Surface-enhanced Raman scattering of 4-aminothiophenol in assemblies of nanosized particles and the macroscopic surface of silver

被引:180
作者
Zheng, JW [1 ]
Zhou, YG
Li, XW
Ji, L
Lu, TH
Gu, RA
机构
[1] Suzhou Univ, Dept Chem, Suzhou 215006, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
关键词
D O I
10.1021/la011706p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Assemblies consisting of nanosized silver particles, 4-aminothiophenol, and the smooth macroscopic surface of silver metal (Ag/PATP/Ag) were prepared and characterized by surface-enhanced Raman spectroscopy. The Raman spectrum of 4-aminothiophenol in the assemblies is similar to that obtained on the electrochemically roughened electrode, although spectral differences, including slight frequency shifts and changes in relative intensity of the characteristic bands, were observed. The enhancement of the spectrum of 4-aminothiophenol in the assemblies is ascribed to the electromagnetic coupling between the silver particles and the surface of the silver metal. The fact that only the SERS spectrum of 4-aminothiophenol was observed for the assembly, where 4-aminothiophenol is partially replaced with N,N'-diphenylthiourea, demonstrates that the electromagnetic field is mainly localized in the region between the silver particles and the surface of the silver metal.
引用
收藏
页码:632 / 636
页数:5
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共 47 条
[1]   Self-assembly of a two-dimensional superlattice of molecularly linked metal clusters [J].
Andres, RP ;
Bielefeld, JD ;
Henderson, JI ;
Janes, DB ;
Kolagunta, VR ;
Kubiak, CP ;
Mahoney, WJ ;
Osifchin, RG .
SCIENCE, 1996, 273 (5282) :1690-1693
[2]   Dendrimer-modified silicon oxide surfaces as platforms for the deposition of gold and silver colloid monolayers: Preparation method, characterization, and correlation between microstructure and optical properties [J].
Bar, G ;
Rubin, S ;
Cutts, RW ;
Taylor, TN ;
Zawodzinski, TA .
LANGMUIR, 1996, 12 (05) :1172-1179
[3]   Near-infrared luminescence from small gold nanocrystals [J].
Bigioni, TP ;
Whetten, RL ;
Dag, Ö .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (30) :6983-6986
[4]   Preparation and characterization of Ag colloid monolayers [J].
Bright, RM ;
Musick, MD ;
Natan, MJ .
LANGMUIR, 1998, 14 (20) :5695-5701
[5]   Surface-enhanced Raman scattering [J].
Campion, A ;
Kambhampati, P .
CHEMICAL SOCIETY REVIEWS, 1998, 27 (04) :241-250
[6]   COLLOIDAL METAL-FILMS AS A SUBSTRATE FOR SURFACE-ENHANCED SPECTROSCOPY [J].
CHUMANOV, G ;
SOKOLOV, K ;
GREGORY, BW ;
COTTON, TM .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (23) :9466-9471
[7]   Reversible tuning of silver quantum dot monolayers through the metal-insulator transition [J].
Collier, CP ;
Saykally, RJ ;
Shiang, JJ ;
Henrichs, SE ;
Heath, JR .
SCIENCE, 1997, 277 (5334) :1978-1981
[8]   Screening and enrichment of metal nanoparticles with novel optical properties [J].
Emory, SR ;
Nie, S .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (03) :493-497
[9]   An electrochemical coulomb staircase: Detection of single electron-transfer events at nanometer electrodes [J].
Fan, FRF ;
Bard, AJ .
SCIENCE, 1997, 277 (5333) :1791-1793
[10]   Application of attenuated total reflection surface-plasmon-polariton Raman spectroscopy to gold and copper [J].
Futamata, M .
APPLIED OPTICS, 1997, 36 (01) :364-375