Structure of the Chromium(III) salt [Cp2Cr]+[CpCrCl3]-

被引：7

作者：

Aldridge, S ^{[1
]}

Shang, MY ^{[1
]}

Fehlner, TP ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197011256

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, bis(eta(5)-pentamethylcyclopentadienyl)chromium(III) trichloro(eta(5)-pentamethylcyclopentadienyl)chromium(III), [Cr(C10H15)(2)][CrCl3(C10H15)], is a salt consisting of discrete anionic [{eta(5)-C-5(CH3)(5)}CrCl3](-) and cationic [{eta(5)-C-5(CH3)(5)}(2)Cr](+) chromium(III) species. The anion adopts a 'three-legged piano-stool' structure, whereas the cation displays a staggered orientation of the C-5 rings and approximates to D-5d local symmetry. The Cr-C distances range from 2.177 (5) to 2.208 (4) Angstrom in the cation and from 2.234 (4) to 2.265 (5) Angstrom in the anion; Cr-Cl distances in the anion fall in the range 2.320 (1)-2.331 (1) Angstrom.

引用

页码：47 / 49

页数：3

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Structure of the Chromium(III) salt [Cp2*Cr]+[Cp*CrCl3]-

Structure of the Chromium(III) salt [Cp2Cr]+[CpCrCl3]-