Enhancement of the phosphorescence of organic luminophores upon interaction with a mercury trifunctional Lewis acid

被引：103

作者：

Omary, MA ^{[1
]}

Kassab, RM

Haneline, MR

Elbjeirami, O

Gabbai, FP

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[2] Texas A&M Univ, College Stn, TX 77843 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 07期

关键词：

D O I：

10.1021/ic034066h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of the trinuclear mercury(II) complex [(sigmaC(6)F(4)Hg)(3)] (1) and pyrene leads to the formation of the 1:1 adduct 1.pyrene. The crystal structure of this adduct reveals the existence of supramolecular stacks in which molecules of 1 and molecules of pyrene alternate along the infinite chains. Steady-state and time-resolved photoluminescence measurements indicate the occurrence of a heavy atom effect which results in red, green, and blue (RGB) phosphorescent emissions for 1.pyrene, 1.naphthalene, and 1.biphenyl, respectively.

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页码：2176 / 2178

页数：3

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