The [4+2], [2+2] strategy for the construction of the AB taxane ring system

被引：17

作者：

Phansavath, P ^{[1
]}

Aubert, C ^{[1
]}

Malacria, M ^{[1
]}

机构：

[1] Univ Paris 06, Lab Chim Organ Synth, CNRS, F-75252 Paris, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(97)10867-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The construction of the AB taxane ring system through a [4+2] reaction and Co(I)-[2+2] cyclization is presented. For the first time, CpCo(CO)(2) catalyzes the ring closure of strained polyunsaturated triynic compound into eight-membered ring. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1561 / 1564

页数：4

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