Preparation and characterization of luminescent thin films doped with rare earth (Tb3+, Eu3+) complexes derived from a sol-gel process

被引:9
作者
Meng, QG [1 ]
Zhang, HJ [1 ]
Wang, SB [1 ]
Fu, LS [1 ]
Zheng, YX [1 ]
Yang, KY [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
基金
中国国家自然科学基金;
关键词
sol-gel; luminescent thin films; RE;
D O I
10.1016/S0167-577X(00)00107-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sol-gel derived luminescent thin films doped with rare earth (RE) complexes were prepared using an in-situ synthesis method with a two-step hydrolysis process and the luminescence spectra were measured. Fluorescence Lifetime and thermal stability were investigated. The results show that a broad excitation band indicates the formation of RE complexes in the solid thin films. RE ions, which are restrained in a silica matrix, present longer lifetime and higher thermal stability than that in DMF/PVB films containing the corresponding pure complexes. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:213 / 216
页数:4
相关论文
共 19 条
[1]   Optical biosensing of gaseous nitric oxide using spin-coated sol-gel thin films [J].
Aylott, JW ;
Richardson, DJ ;
Russell, DA .
CHEMISTRY OF MATERIALS, 1997, 9 (11) :2261-2263
[2]   ANALYSIS OF FLUORESCENCE SPECTRA OF RARE-EARTH CHELATES .2. DIPYRIDYL COMPLEXES OF EUROPIC CHLORIDE [J].
FILIPESCU, N ;
BJORKLUND, S ;
MCAVOY, N ;
DEGNAN, J .
JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (07) :2895-+
[3]  
Fu LS, 1999, CHEM RES CHINESE U, V15, P100
[4]  
Fu LS, 1999, J MATER SCI TECHNOL, V15, P187
[5]   LANTHANIDE COMPLEXES .3. COMPLEXES OF 2,2'-DIPYRIDYL WITH LANTHANIDE CHLORIDES THIOCYANATES ACETATES AND NITRATES [J].
HART, FA ;
LAMING, FP .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (08) :1825-&
[6]   LUMINESCENCE PROPERTY OF THE TERBIUM BIPYRIDYL COMPLEX INCORPORATED IN SILICA MATRIX BY A SOL-GEL METHOD [J].
JIN, T ;
TSUTSUMI, S ;
DEGUCHI, Y ;
MACHIDA, KI ;
ADACHI, GY .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (10) :L195-L197
[7]   Luminescence properties of lanthanide complexes incorporated into sol-gel derived inorganic-organic composite materials [J].
Jin, T ;
Inoue, S ;
Tsutsumi, S ;
Machida, K ;
Adachi, GY .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 223 (1-2) :123-132
[8]   Luminescence characteristics of the lanthanide complex incorporated into an ORMOSIL matrix using a sol-gel method [J].
Jin, T ;
Tsutsumi, S ;
Deguchi, Y ;
Machida, K ;
Adachi, G .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (10) :3333-3335
[9]   Preparation and luminescence characteristics of the europium and terbium complexes incorporated into a silica matrix using a sol-gel method [J].
Jin, T ;
Tsutsumi, S ;
Deguchi, Y ;
Machida, K ;
Adachi, G .
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 252 (1-2) :59-66
[10]  
KAUFMAN VR, 1986, LANGMUIR, V717, P2