Drying of solvent coated polymer films

被引:57
作者
Alsoy, S [1 ]
Duda, JL [1 ]
机构
[1] Penn State Univ, Dept Chem Engn, Ctr Study Polymer Solvent Syst, University Pk, PA 16802 USA
关键词
convection; diffusion; film; heat transfer; immobilized boundary; mass transfer; polymer-solvent system; volume average velocity;
D O I
10.1080/07373939808917390
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The ability to predict the drying behavior of coating is of great importance to the coating industry. For this purpose, the model developed by Vrentas and Vrentas(19) has been used to predict the concentration profile as well as the thickness and the temperature change of the polymer film as a function of time. The model incorporates the coupling between heat and mass transfer and diffusion induced convection which occurs when a single layer of a binary polymer solution is dried in a convection heated oven. The model was solved numerically by using the finite difference approximation and it was applied to the well characterized polyvinylacetate(PVAC)-toluene system. The effects of operating conditions on the residual solvent level were investigated. The validity of the model was confirmed by using two sets of data available for the drying of polystyrene(PS)toluene and PVAC-toluene systems.
引用
收藏
页码:15 / 44
页数:30
相关论文
共 21 条
[1]   MATHEMATICAL-ANALYSIS OF FACTORS INFLUENCING SKIN THICKNESS OF ASYMMETRIC REVERSE-OSMOSIS MEMBRANES [J].
ANDERSON, JE ;
ULLMAN, R .
JOURNAL OF APPLIED PHYSICS, 1973, 44 (10) :4303-4311
[2]   GRAVIMETRIC ANALYSIS OF MEMBRANE CASTING .1. CELLULOSE-ACETATE ACETONE BINARY CASTING SOLUTIONS [J].
ATAKA, M ;
SASAKI, K .
JOURNAL OF MEMBRANE SCIENCE, 1982, 11 (01) :11-25
[3]   MODELING OF DRYING OF COATINGS - EFFECT OF THE THICKNESS, TEMPERATURE AND CONCENTRATION OF SOLVENT [J].
BLANDIN, HP ;
DAVID, JC ;
VERGNAUD, JM ;
ILLIEN, JP ;
MALIZEWICZ, M .
PROGRESS IN ORGANIC COATINGS, 1987, 15 (02) :163-172
[4]   COMPETING DRYING AND REACTION-MECHANISMS IN THE FORMATION OF SOL-TO-GEL FILMS, FIBERS, AND SPHERES [J].
CAIRNCROSS, RA ;
FRANCIS, LF ;
SCRIVEN, LE .
DRYING TECHNOLOGY, 1992, 10 (04) :893-923
[5]  
CAIRNCROSS RA, 1994, AICHE SPR NAT M ATL
[6]   PREPARATION OF REVERSE-OSMOSIS MEMBRANES - A NUMERICAL-ANALYSIS OF ASYMMETRIC MEMBRANE FORMATION BY SOLVENT EVAPORATION FROM CELLULOSE-ACETATE CASTING SOLUTIONS [J].
CASTELLARI, C ;
OTTANI, S .
JOURNAL OF MEMBRANE SCIENCE, 1981, 9 (1-2) :29-41
[7]  
DAUBERT TE, 1994, PHYSICAL THERMODYNAM
[8]  
DENNIS JE, 1983, NUMERICAL METHODS UN, P111
[9]  
DUDA JL, 1982, AICHE J, V28, P285
[10]  
HONG S, 1994, THESIS PENNSYLVANIA