Fabrication and structural characterization of electro-spun polybenzimidazol-derived carbon nanofiber by graphitization

被引:28
作者
Kim, C
Kim, YJ
Kim, YA
机构
[1] Chonnam Natl Univ, Fac Appl Chem Engn, Kwangju 500757, South Korea
[2] Shinshu Univ, Fac Engn, Nagano 3808553, Japan
基金
新加坡国家研究基金会;
关键词
carbon nanofibers; electro-spinning; crystal growth; order-disorders effects;
D O I
10.1016/j.ssc.2004.08.035
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Here we fabricate hi.-h-purity carbon sheets consisting of 250 nm nanofibers through the fibre formation of poly (benzimidazol) by electro-spinning and subsequent heat treatment up to 3000 degreesC without the stabilization process (the most time-consuming step). The non-graphitic character of these nanofibers is due to: (1) the low graphitization-ability of the polymer itself, (2) the limited graphitization of the size effect (small diameter) (3) the existence of internal pores formed during the electrospinning process. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:567 / 571
页数:5
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