Hydrogen bonding and cooperativity effects on the assembly of carbohydrates

被引：30

作者：

de la Paz, ML ^{[1
]}

Jiménez-Barbero, J ^{[1
]}

Vicent, C ^{[1
]}

机构：

[1] CSIC, Inst Quim Organ, Dept Quim Organ Biol, E-28006 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 04期

关键词：

D O I：

10.1039/a708386f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effect of intramolecular hydrogen bonds on the cooperative assembly of carbohydrate derivatives has been evaluated; the 1,3-diaxial OH ... OH intramolecular hydrogen bond is at the origin of the dimerization of diol 1; and one intermolecular OH ... OH bond accounts for 2.5 kcal mol(-1) in CDCl3 and 3 kcal mol(-1) in CDCl3-CCl4.

引用

页码：465 / 466

页数：2

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