Zeolite membranes -: state of their development and perspective

被引:658
作者
Caro, J [1 ]
Noack, M [1 ]
Kölsch, P [1 ]
Schäfer, R [1 ]
机构
[1] Berlin Adlershof eV, Inst Angew Chem, D-12489 Berlin, Germany
关键词
zeolite membrane; inorganic membrane; sol-gel membrane; MFI membrane; permselectivity; mixture separation factor;
D O I
10.1016/S1387-1811(99)00295-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
An ideal zeolite membrane combines the general advantages of inorganic membranes (temperature stability, solvent resistance) with a perfect shape selectivity. Due to their "molecular sieve" function, zeolite membranes can principally discriminate the components of gaseous or liquid mixtures dependent on their molecular size. This molecular sieving principle requires a pinhole- and crack-free zeolite membrane. Remarkable separation effects can also be achieved by the interplay of mixture adsorption and mixture diffusion. This review focuses on composite membranes which consist of a zeolite top layer on a mesoporous ceramic or metal support. Special attention is given to supported MFI membranes. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:3 / 24
页数:22
相关论文
共 155 条
  • [1] [Anonymous], MEMBRANE SCI TECHNOL
  • [2] [Anonymous], J MEMBR SCI
  • [3] MEMBRANE CATALYSIS - WHERE IS IT NOW, WHAT NEEDS TO BE DONE
    ARMOR, JN
    [J]. CATALYSIS TODAY, 1995, 25 (3-4) : 199 - 207
  • [4] ASADA T, COMMUNICATION
  • [5] Permeation of aromatic hydrocarbon vapors through silicalite-zeolite membranes
    Baertsch, CD
    Funke, HH
    Falconer, JL
    Noble, RD
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (18) : 7676 - 7679
  • [6] Temperature dependence of one-component permeation through a silicalite-1 membrane
    Bakker, WJW
    vandenBroeke, LJP
    Kapteijn, F
    Moulijn, JA
    [J]. AICHE JOURNAL, 1997, 43 (09) : 2203 - 2214
  • [7] Preparation of zeolite UTD-1 films by pulsed laser ablation: Evidence for oriented crystal growth
    Balkus, KJ
    Munoz, T
    Gimon-Kinsel, ME
    [J]. CHEMISTRY OF MATERIALS, 1998, 10 (02) : 464 - +
  • [8] Zeolite coatings on three-dimensional objects via laser ablation
    Balkus, KJ
    Scott, AS
    [J]. CHEMISTRY OF MATERIALS, 1999, 11 (02) : 189 - 191
  • [9] SORPTION ISOTHERMS OF ALCOHOLS IN ZEOLITE-FILLED SILICONE-RUBBER AND IN PVA-COMPOSITE MEMBRANES
    BARTELSCASPERS, C
    TUSELLANGER, E
    LICHTENTHALER, RN
    [J]. JOURNAL OF MEMBRANE SCIENCE, 1992, 70 (01) : 75 - 83
  • [10] STABILIZATION OF ALUMINA TOWARD THERMAL SINTERING BY SILICON ADDITION
    BEGUIN, B
    GARBOWSKI, E
    PRIMET, M
    [J]. JOURNAL OF CATALYSIS, 1991, 127 (02) : 595 - 604