9,10-dimetallatriptycenes of group 14: a structural study

被引：8

作者：

Dam, MA

de Kanter, FJJ

Bickelhaupt, F

Smeets, WJJ

Spek, AL

Fornies-Camer, J

Cardin, C

机构：

[1] Vrije Univ Amsterdam, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res, Vakgroep Kristal Structuurchem, NL-3584 CH Utrecht, Netherlands

[3] Univ Reading, Dept Chem, Reading RG4 9BB, Berks, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 550卷 / 1-2期

关键词：

silicon; germanium; tin; 9,10-dimetallatriptycenes; ortho-phenylenemagnesium;

D O I：

10.1016/S0022-328X(97)00237-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From ortho-phenylenemagnesium (1), 9-phenyl-9-germa-10-silatriptycene (5) was prepared via a simple one pot procedure. The previously prepared 9-methyl-10-phenyl-9,10-digermatriptycene (4) and 5 are the first germanium-containing 9,10-dimetallatriptycenes to be structurally characterised. The availability of these structural data allows a comparative discussion of 9,10-dimetallatriptycenes of Group 14. (C) 1998 Elsevier Science B.V.

引用

页码：347 / 353

页数：7

共 24 条

[1] ALLEMAND J, 1979, CRYST STRUCT COMMUN, V8, P927
[2] TETRA-PARA-TOLYL COMPOUNDS PARA-TOL4SI AND PARA-TOL4GE - CONFIGURATION OF TETRARYL METHANEANALOGS AR4M (M = C,SI,GE,SN,PB)
CHARISSE, M
ROLLER, S
DRAGER, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 427 (01) : 23 - 31
[3] CHIEH PC, 1971, J CHEM SOC A, P3241
[4] 9,10-Dimetallatriptycenes of Group 14: A novel synthetic approach from ortho-phenylenemagnesium
Dam, MA
Akkerman, OS
deKanter, FJJ
Bickelhaupt, F
Veldman, N
Spek, AL
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (09) : 1139 - 1142
[5] DYACHENKO OA, 1976, J STRUCT CHEM+, V17, P426
[6] CRYSTAL AND MOLECULAR-STRUCTURE OF 9,10-DISILADIHYDROANTHRACENE
DYACHENKO, OA
ATOVMYAN, LO
SOBOLEVA, SV
[J]. JOURNAL OF STRUCTURAL CHEMISTRY, 1975, 16 (03) : 478 - 480
[7] DYACHENKO OA, 1974, J STRUCT CHEM, V15, P161
[8] CRYSTAL-STRUCTURE OF 1,4,9,10-TETRAMETHYLTRIPTYCENE AND BARRIERS TO ROTATION OF BRIDGEHEAD-METHYL GROUPS IN 1,4,9,10-TETRAMETHYL-TRIPTYCENE AND 1,4-DICHLORO-9,10-DIMETHYL-TRIPTYCENE
IMASHIRO, F
HIRAYAMA, K
TAKEGOSHI, K
TERAO, T
SAIKA, A
TAIRA, Z
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1988, (08): : 1401 - 1408
[9] AUTOMATIC PROCESSING OF ROTATION DIFFRACTION DATA FROM CRYSTALS OF INITIALLY UNKNOWN SYMMETRY AND CELL CONSTANTS
KABSCH, W
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 : 795 - 800
[10] CRYSTAL-STRUCTURE OF 1,2,3,4-TETRACHLORO-9-T-BUTYLTRIPTYCENE
MIKAMI, M
TORIUMI, K
KONNO, M
SAITO, Y
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (OCT15): : 2474 - 2478

← 1 2 3 →