Electrochemical synthesis of alkyl nitroaromatic compounds

被引：20

作者：

Gallardo, I ^{[1
]}

Guirado, G ^{[1
]}

Marquet, J ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 02期

关键词：

D O I：

10.1021/jo025898k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl nitroaromatic compounds were readily prepared via nucleophilic aromatic substitution for hydrogen or a heteroatom by electrochemical oxidation of the a-complex. Butyllithium and butylmagnesium chloride were used as nucleophiles, and several nitrocompounds were tested to explore the possibilities of the NASH and NASX reactions promoted electrochemically.

引用

页码：631 / 633

页数：3

共 29 条

[1] [Anonymous], 1991, NUCLEOPHILIC AROMATI
[2] ARTOLI G, 1998, J CHEM SOC P1, P692
[3] CONJUGATE ADDITION OF RMGX TO NITROARENES - VERY USEFUL METHOD OF ALKYLATION OF AROMATIC NITRO-COMPOUNDS
BARTOLI, G
BOSCO, M
BACCOLINI, G
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (03) : 522 - 524
[4] BARTOLI G, 1997, J CHEM SOC P1, P884
[5] BARTOLI G, 1998, J CHEM SOC P1, P692
[6] Buehler C.A., 1970, SURVEY ORGANIC SYNTH
[7] CAREY FA, 1991, ADV ORGANIC SYNTHE A
[8] CHUPAKHIN ON, 1994, NUCLEOPJHILIC AROMAT
[9] FRANCK HG, 1987, IND AROMATIC CHEM RA
[10] Gallardo I, 2002, EUR J ORG CHEM, V2002, P261, DOI 10.1002/1099-0690(20021)2002:2<261::AID-EJOC261>3.0.CO

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