Channel mixing effects in the dissociative recombination of H3+ with slow electrons

被引:51
作者
Schneider, IF
Orel, AE
Suzor-Weiner, A
机构
[1] Univ Havre, Lab Mecan, F-76058 Le Havre, France
[2] Univ Paris Sud, Photophys Mol Lab, F-91405 Orsay, France
[3] Natl Inst Lasers Plasma & Radiat Phys, Bucharest, Romania
[4] Univ Calif Lawrence Livermore Natl Lab, Dept Appl Sci, Livermore, CA 94550 USA
[5] Chim Phys Lab, F-75234 Paris, France
关键词
D O I
10.1103/PhysRevLett.85.3785
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We discuss the low-energy dissociative recombination of H-3(+) which strongly influences the abundance: of this ion in diffuse interstellar molecular clouds. The kinetic couplings between the ionization continuum and the dissociative ground state of H-3 have been used as input to a two-dimensional wave packet calculation of dissociation dynamics. The cross section obtained for direct dissociative recombination is much smaller than the latest experimental results. However, a multichannel quantum defect treatment shows that an indirect mechanism via bound Rydberg states of H-3 prevails for this process.
引用
收藏
页码:3785 / 3788
页数:4
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