Palladium-catalyzed allylation of imines with allyl alcohols

被引:55
作者
Shimizu, M
Kimura, M
Watanabe, T
Tamaru, Y
机构
[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 8528521, Japan
[2] Nagasaki Univ, Grad Sch Sci & Technol, Nagasaki 8528521, Japan
关键词
D O I
10.1021/ol047609f
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A catalytic system, Pd(OAC)(2)(10 mol %)-P(n-Bu)(3) (20 mol %)-Et3B (360 mol %), promotes allylic alcohols to undergo the allylation of anisidine-imines of aromatic and aliphatic aldehydes and furnishes homoallylamines in good to moderate yields. The reaction shows unique stereoselectivity, giving ant isomers selectively.
引用
收藏
页码:637 / 640
页数:4
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