A Molecular Double Decker: Extending the Limits of Current Metal-Molecule Hybrid Structures

被引：30

作者：

Eberle, Felix ^{[3
]}

Saitner, Marc ^{[1
]}

Boyen, Hans-Gerd ^{[1
]}

Kucera, Jan ^{[4
]}

Gross, Axel ^{[4
]}

Romanyuk, Andriy ^{[5
]}

Oelhafen, Peter ^{[5
]}

D'Olieslaeger, Marc ^{[1
,2
]}

Manolova, Mila ^{[3
]}

Kolb, Dieter M. ^{[3
]}

机构：

[1] Hasselt Univ, Inst Mat Res IMO, B-3590 Diepenbeek, Belgium

[2] IMEC, Div IMOMEC, B-3590 Diepenbeek, Belgium

[3] Univ Ulm, Inst Elektrochem, D-89069 Ulm, Germany

[4] Univ Ulm, Inst Theoret Chem, D-89069 Ulm, Germany

[5] Univ Basel, Dept Phys, CH-4056 Basel, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 02期

基金：

瑞士国家科学基金会;

关键词：

density functional calculations; electrochemical deposition; molecular double deckers; organic-inorganic hybrid composites; self-assembly; X-RAY; DEPOSITION; 4-MERCAPTOPYRIDINE; MONOLAYERS; INTERFACES; COPPER;

D O I：

10.1002/anie.200905339

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical Equation Presented" Towards the third dimension: A new type of organic-inorganic hybrid comprises two independent molecular layers separated by a metal monolayer and sandwiched between outer electrodes (see picture). The interlayer reveals metallic properties despite its reduced dimensions and the presence of chemical bonds at both sides. It might be useful as an intermediate electrode to control charge transport through molecule-based devices. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA."

引用

页码：341 / 345

页数：5

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