Synthesis and luminescence properties of a new polyfluorene copolymer with regulated solubility

被引：14

作者：

Charas, A

Morgado, J

Alcácer, L

Brogueira, P

Cacialli, F

机构：

[1] Univ Tecn Lisboa, Inst Telecomunicacoes, IST, P-1049001 Lisbon, Portugal

[2] Univ Tecn Lisboa, Dep Eng Quim, Inst Super Tecn, P-1049001 Lisbon, Portugal

[3] Univ Tecn Lisboa, Dept Fis, Inst Super Tecn, P-1049001 Lisbon, Portugal

[4] UCL, London Ctr Nanotechnol, Dept Phys, London WC1E 6BT, England

来源：

SYNTHETIC METALS | 2004年 / 147卷 / 1-3期

关键词：

BTBOX; 9,9-dioctylfluore; UV irradiation;

D O I：

10.1016/j.synthmet.2004.05.025

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We report on the synthesis and luminescence properties of a new random fluorene-based copolymer, BTBOX, combining 9,9-dioctylfluorene, benzothiadiazole and phenylene units substituted with pendant oxetane groups, which can undergo a ring-opening polymerisation. BTBOX exhibits efficient green-yellow emission. Upon UV irradiation of solid films of BTBOX containing a photoacid the oxetane groups polymerise, leading to the formation of an insoluble crosslinked network, r-BTBOX. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：275 / 279

页数：5

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