Co(III)-alkylperoxo complexes: Syntheses, structure-reactivity correlations, and use in the oxidation of hydrocarbons

被引：125

作者：

Chavez, FA ^{[1
]}

Mascharak, PK ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2000年 / 33卷 / 08期

关键词：

D O I：

10.1021/ar990089h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystalline [LCoIII-OOR] complexes with strong-field ligands, L, afford ROO. and RO. radicals upon mild heating in solution. This fact allows oxidation of hydrocarbons by these complexes under mild conditions. The extent of hydrocarbon oxidation by discrete [LCoIII-OOR] complexes depends on the nature of L, the solvent, the temperature, and the presence of other M(II) ions. Such systems are catalytic in the presence of excess ROOH.

引用

页码：539 / 545

页数：7

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