Investigation into the nature of the oxoruthenate species used to mediate the oxidation of an organic substrate by hypochlorite in a biphasic system

被引：14

作者：

Mills, A ^{[1
]}

Holland, C ^{[1
]}

机构：

[1] Univ Wales, Swansea, W Glam, Wales

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1997年 / 10期

关键词：

D O I：

10.1039/a704210h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrophilic sodium perruthenate, rather than lipophilic ruthenium tetraoxide, is the mediator in the oxidation of octan-2-ol by sodium hypochlorite in a water-carbon tetrachloride (or dichloromethane) biphasic system; as a consequence, oxidation occurs at the phase boundary and is promoted by stirring or ultrasound.

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页码：368 / 369

页数：3

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