o-Carborane-assisted Lewis acidity enhancement of triarylboranes

被引：93

作者：

Huh, Jung Oh ^{[1
]}

Kim, Hyungjun ^{[1
]}

Lee, Kang Mun ^{[1
]}

Lee, Yoon Sup ^{[1
]}

Do, Youngkyu ^{[1
]}

Lee, Min Hyung ^{[2
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

[2] Univ Ulsan, Dept Chem, Ulsan 680749, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 07期

基金：

新加坡国家研究基金会;

关键词：

ELECTRON-ACCEPTING ABILITY; METAL CHELATION; CATIONIC BORANE; FLUORIDE; ACTIVATION; WATER; COMPLEXATION; REACTIVITY; CAPTURE; SYSTEMS;

D O I：

10.1039/b918263b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The introduction of an o-carborane cage into the triarylborane significantly enhances the Lewis acidity of the boron atom leading to large increase in fluoride ion affinity.

引用

页码：1138 / 1140

页数：3

共 28 条

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