Synthesis and characterization of some Cr(III), Fe(III) and Zr(IV) compounds with substituted o-hydroxy benzophenone

被引:4
作者
Foca, N
Lisa, G
Rusu, I
机构
[1] Gh Asachi Tech Univ, Fac Ind Chem, Dept Inorgan Chem, Iasi 700050, Romania
[2] Gh Asachi Tech Univ, Fac Ind Chem, Dept Phys Chem, Iasi 700050, Romania
关键词
chrome; iron; melted urea; thermal behaviour; zirconium;
D O I
10.1023/B:JTAN.0000042171.81071.e3
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work presents our data concerning the synthesis and characterization of some Cr(III), Fe( III) and Zr(IV) complexes with substituted (2-hydroxy-4-methoxy-phenyl)-phenyl-methanone -C14H12O3, denoted by (L1). The synthesis of these complex compounds was performed using melted urea as reaction medium. The obtained complexes have been studied by chemical analysis, IR spectroscopy, X-ray diffraction and thermogravimetric analysis. Based on the data resulting from the thermal behaviour of the studied complex compounds, the kinetic parameters of the thermal decomposition reactions have been determined.
引用
收藏
页码:239 / 249
页数:11
相关论文
共 22 条
[1]  
BELLANY J, 1968, ADV INFRARED GROUP F, P232
[2]   Computational aspects of kinetic analysis Part A: The ICTAC kinetics project-data, methods and results [J].
Brown, ME ;
Maciejewski, M ;
Vyazovkin, S ;
Nomen, R ;
Sempere, J ;
Burnham, A ;
Opfermann, J ;
Strey, R ;
Anderson, HL ;
Kemmler, A ;
Keuleers, R ;
Janssens, J ;
Desseyn, HO ;
Li, CR ;
Tang, TB ;
Roduit, B ;
Malek, J ;
Mitsuhashi, T .
THERMOCHIMICA ACTA, 2000, 355 (1-2) :125-143
[3]   Prediction of the isothermal behaviour of solid-gas systems from non-isothermal data - Differential isoconversional procedure [J].
Budrugeac, P ;
Segal, E .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 72 (03) :831-837
[4]  
FURMAN N, 1963, STANDARD METHODS CHE, P212
[5]  
KIRKBRINGHT GF, 1974, ATOMIC ABSORPTION FL, P123
[6]  
KLUY P, 1974, XRAY DIFFRACTION PRO, P93
[7]  
NAKAMPTO K, 1963, INFRARED SPECTRA INO
[8]  
NENITESCU CD, 1980, CHIMIE ORG
[9]  
POPA G, 1971, CHIMIE ANAL CANTITAT, P221
[10]  
POTTS WJ, 1964, CHEM INFRARED SPECTR, P322