Nitrogen-doped SiO2/TiO2 core/shell nanoparticles as highly efficient visible light photocatalyst

被引:87
作者
Kim, Chanhoi [1 ]
Choi, Moonjung [1 ]
Jang, Jyongsik [1 ]
机构
[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151742, South Korea
关键词
Nitrogen-doped TiO2; Template; Photocatalyst; Calcination temperature; Visible light; CONDUCTING-POLYMER NANOMATERIALS; TIO2; DEGRADATION; PERFORMANCE; FABRICATION; CATALYST; SULFUR; CARBON; ROUTE; SIZE;
D O I
10.1016/j.catcom.2009.11.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
Nitrogen-doped SiO2/TiO2 core/shell nanoparticles with uniform diameter were fabricated using SiO2 template sol-gel method. Furthermore, the relationship between the temperate of calcination and photocatalytic efficiency was also investigated in the viewpoint of organic pollutant decomposition. The morphology and characteristics of nitrogen-doped SiO2/TiO2 core/shell nanoparticles were studied by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), X-ray powder diffraction (XRD), and specific surface area. The results demonstrated that nitrogen-doped TiO2 layer was successfully coated onto the SiO2 nanoparticles without aggregation. Nitrogen-doped SiO2/TiO2 core/shell nanoparticles exhibited highly efficient photocatalytic activity under visible light irradiation due to high nitrogen doping level and surface area. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:378 / 382
页数:5
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