High-performance surface-enhanced Raman scattering sensors based on Ag nanoparticles-coated Si nanowire arrays for quantitative detection of pesticides

被引:130
作者
Wang, X. T. [1 ,2 ]
Shi, W. S. [1 ]
She, G. W. [1 ]
Mu, L. X. [1 ]
Lee, S. T. [1 ,3 ,4 ]
机构
[1] Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] City Univ Hong Kong, Dept Phys & Mat Sci, Hong Kong, Hong Kong, Peoples R China
[4] City Univ Hong Kong, COSDAF, Hong Kong, Hong Kong, Peoples R China
关键词
elemental semiconductors; nanosensors; nanowires; organic compounds; semiconductor quantum wires; silicon; silver; surface enhanced Raman scattering; SILVER; SPECTROSCOPY; SILICON; MOLECULES; ZEOLITE; FILMS;
D O I
10.1063/1.3300837
中图分类号
O59 [应用物理学];
学科分类号
摘要
A surface-enhanced Raman scattering (SERS) sensor made of Ag nanoparticles-coated Si nanowire (SiNW) arrays was fabricated for the quantitative detection of Carbaryl (an important nitrogen pesticide). H-terminated SiNWs were capable of reducing silver ions, leading to uniform deposition of silver nanoparticles on SiNW arrays. Such wire arrays exhibited a superior detection sensitivity of 10(-17) M Rodamine 6G with high reproducibility. The sensor also enabled high sensitivity, reproducibility, and stability detection of Carbaryl. Significantly, the linear relation between the logarithmic concentrations and Raman peak intensities provided quantitative detection of Carbaryl.
引用
收藏
页数:3
相关论文
共 19 条
[1]   Study of silver films over silica beads as a surface-enhanced Raman scattering (SERS) substrate for detection of benzoic acid [J].
Bao, LL ;
Mahurin, SM ;
Liang, CD ;
Dai, S .
JOURNAL OF RAMAN SPECTROSCOPY, 2003, 34 (05) :394-398
[2]   Surface-enhanced Raman scattering of small molecules from silver-coated silicon nanopores [J].
Chan, S ;
Kwon, S ;
Koo, TW ;
Lee, LP ;
Berlin, AA .
ADVANCED MATERIALS, 2003, 15 (19) :1595-+
[3]   Direct observation of size-dependent optical enhancement in single metal nanoparticles [J].
Emory, SR ;
Haskins, WE ;
Nie, SM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (31) :8009-8010
[4]   Gold-Coated Nanorod Arrays as Highly Sensitive Substrates for Surface-Enhanced Raman Spectroscopy [J].
Fan, J. -G. ;
Zhao, Y. -P. .
LANGMUIR, 2008, 24 (24) :14172-14175
[5]   Metallization of Silicon Nanowires and SERS Response from a Single Metallized Nanowire [J].
Fang, Cheng ;
Agarwal, Ajay ;
Widjaja, Effendi ;
Garland, Marc V. ;
Wong, She Mein ;
Linn, Linn ;
Khalid, Nizamudin Mohamed ;
Salim, Shaik Mohamed ;
Balasubramanian, Narayanan .
CHEMISTRY OF MATERIALS, 2009, 21 (15) :3542-3548
[6]   Seeded-growth approach to fabrication of silver nanoparticle films on silicon for electrochemical ATR surface-enhanced IR absorption spectroscopy [J].
Huo, Sheng-Juan ;
Xue, Xiao-Kang ;
Li, Qiao-Xia ;
Xu, Su-Fan ;
Cai, Wen-Bin .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (51) :25721-25728
[7]   Photoluminescence and Raman spectroscopy as probes to investigate silver and gold dicyanide clusters doped in A-zeolite and their photoassisted degradation of carbaryl [J].
Kanan, SA ;
Tripp, CP ;
Austin, RN ;
Patterson, HH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (39) :9441-9448
[8]   Identifying framework titanium in TS-1 zeolite by UV resonance Raman spectroscopy [J].
Li, C ;
Xiong, G ;
Liu, JK ;
Ying, PL ;
Xin, Q ;
Feng, ZC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (15) :2993-2997
[9]   Surface enhanced Raman spectroscopy of individual rhodamine 6G molecules on large Ag nanocrystals [J].
Michaels, AM ;
Nirmal, M ;
Brus, LE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (43) :9932-9939
[10]   Motility of Metal Nanoparticles in Silicon and Induced Anisotropic Silicon Etching [J].
Peng, Kuiqing ;
Lu, Aijiang ;
Zhang, Ruiqin ;
Lee, Shuit-Tong .
ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (19) :3026-3035