A highly reactive triboracyclobutane and its dianion:: Two-electron homoaromatics with nonclassical and classical σ skeletons

被引:9
作者
Amseis, P
Mesbah, W
Präsang, C
Hofmann, M
Geiseler, G
Massa, W
Berndt, A
机构
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
[2] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
关键词
D O I
10.1021/om021046z
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first triboracyclobutane, 2c, a two-electron homoaromatic having a nonclassical a skeleton, was generated at -80 C and stabilized as its dianion 2a2-, which was characterized by the crystal structure determination of its dilithium salt and which possesses a classical a skeleton.
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页码:1594 / 1596
页数:3
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