Electrically conducting, Ca-rich brines, rather than water, expected in the Martian subsurface

被引:51
作者
Burt, DM
Knauth, LP
机构
[1] Arizona State Univ, Dept Geol Sci, Tempe, AZ 85287 USA
[2] Lunar & Planetary Inst, Houston, TX 77058 USA
关键词
Mars; brines; subsurface; seeps; evaporites;
D O I
10.1029/2002JE001862
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
[1] If Mars ever possessed a salty liquid hydrosphere, which later partly evaporated and froze down, then any aqueous fluids left near the surface could have evolved to become dense eutectic brines. Eutectic brines, by definition, are the last to freeze and the first to melt. If CaCl2-rich, such brines can remain liquid until temperatures below 220degreesK, close to the average surface temperature of Mars. In the Martian subsurface, in intimate contact with the Ca-rich basaltic regolith, NaCl-rich early brines should have reacted to become Ca-rich. Fractional crystallization (freezing) and partial melting would also drive brines toward CaCl2-rich compositions. In other words, eutectic brine compositions could be present in the shallow subsurface of Mars, for the same reasons that eutectic magma compositions are common on Earth. Don Juan Pond, Antarctica, a CaCl2-rich eutectic brine, provides a possible terrestrial analog, particularly because it is fed from a basaltic aquifer. Owing to their relative density and fluid nature, brines in the Martian regolith should eventually become sandwiched between ice above and salts beneath. A thawing "brine sandwich'' provides one explanation (among many) for the "young gullies'' recently attributed to seepage of liquid water on Mars. Whether or not brine seepage explains the gullies phenomenon, dense, CaCl2-rich brines are to be expected in the deep subsurface of Mars, although they might be somewhat diluted (temperatures permitting) and of variable salt composition. In any case, they should be good conductors of electricity.
引用
收藏
页数:6
相关论文
共 43 条
[1]   Experimental hydrothermal alteration of a martian analog basalt: Implications for martian meteorites [J].
Baker, LL ;
Agenbroad, DJ ;
Wood, SA .
METEORITICS & PLANETARY SCIENCE, 2000, 35 (01) :31-38
[2]   STABILITY OF BRINES ON MARS [J].
BRASS, GW .
ICARUS, 1980, 42 (01) :20-28
[3]   Evaporite mineral assemblages in the nakhlite (martian) meteorites [J].
Bridges, JC ;
Grady, MM .
EARTH AND PLANETARY SCIENCE LETTERS, 2000, 176 (3-4) :267-279
[4]   Alteration assemblages in martian meteorites: Implications for near-surface processes [J].
Bridges, JC ;
Catling, DC ;
Saxton, JM ;
Swindle, TD ;
Lyon, IC ;
Grady, MM .
SPACE SCIENCE REVIEWS, 2001, 96 (1-4) :365-392
[5]   CHLORINE-36 TRACING OF SALINITY SOURCES IN THE DRY VALLEYS OF VICTORIA LAND, ANTARCTICA [J].
CARLSON, CA ;
PHILLIPS, FM ;
ELMORE, D ;
BENTLEY, HW .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1990, 54 (02) :311-318
[6]   A chemical model for evaporites on early Mars: Possible sedimentary tracers of the early climate and implications for exploration [J].
Catling, DC .
JOURNAL OF GEOPHYSICAL RESEARCH-PLANETS, 1999, 104 (E7) :16453-16469
[7]   Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results [J].
Christensen, PR ;
Bandfield, JL ;
Hamilton, VE ;
Ruff, SW ;
Kieffer, HH ;
Titus, TN ;
Malin, MC ;
Morris, RV ;
Lane, MD ;
Clark, RL ;
Jakosky, BM ;
Mellon, MT ;
Pearl, JC ;
Conrath, BJ ;
Smith, MD ;
Clancy, RT ;
Kuzmin, RO ;
Roush, T ;
Mehall, GL ;
Gorelick, N ;
Bender, K ;
Murray, K ;
Dason, S ;
Greene, E ;
Silverman, S ;
Greenfield, M .
JOURNAL OF GEOPHYSICAL RESEARCH-PLANETS, 2001, 106 (E10) :23823-23871
[8]   THE SALTS OF MARS [J].
CLARK, BC ;
VANHART, DC .
ICARUS, 1981, 45 (02) :370-378
[9]   IMPLICATIONS OF ABUNDANT HYGROSCOPIC MINERALS IN MARTIAN REGOLITH [J].
CLARK, BC .
ICARUS, 1978, 34 (03) :645-665
[10]  
CLARK BC, 1993, GEOCHIM COSMOCHIM AC, V57, P4573