Determination of trace elements including platinum in tree bark by ICP mass spectrometry

被引:54
作者
Becker, JS
Bellis, D
Staton, I
McLeod, CW
Dombovari, J
Becker, JS
机构
[1] Forschungszentrum Julich, Zent Abt Chem Anal, D-52425 Julich, Germany
[2] Univ Sheffield, Dept Chem, Ctr Analyt Sci, Sheffield S3 7HF, S Yorkshire, England
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 2000年 / 368卷 / 05期
关键词
D O I
10.1007/s002160000539
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The increasing emission of Pt-group metals from automobile catalytic converters requires the development of highly sensitive procedures for ultratrace analysis of environmental and biological systems. Tree bark, located close to motorway or industrial areas, was utilised as a substrate for collection of airborne particulate matter and samples after digestion (microwave assisted dissolution with HNO(3) and HCl) were analysed by ICP mass spectrometry. The study targeted Pt and other metallic contaminants and involved analysis of some 57 tree bark samples using both quadrupole and double-focusing sector field ICP mass spectrometers. Detection limits for platinum determination in tree bark were 0.03 ng/g (DF-ICP-MS) and 0.2 ng/g (ICP-QMS). The platinum content of the bark samples ranged from 0.07-5.4 ng/g.
引用
收藏
页码:490 / 495
页数:6
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