A hydrophobic nanocapsule controls the photophysics of aromatic molecules by suppressing their favored solution pathways

被引：200

作者：

Kaanumalle, LS

Gibb, CLD

Gibb, BC ^{[1
]}

Ramamurthy, V

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 11期

关键词：

D O I：

10.1021/ja0425381

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Remarkably, anthracene that dimerizes with unit efficiency in solution does not dimerize within the capsule despite forming 2:2 complex. The capsule allows an unprecedented examination of the anthracene excimer. Copyright © 2005 American Chemical Society.

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页码：3674 / 3675

页数：2

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