Hydrothermal synthesis and structural characterization of prototypical organic-inorganic hybrid materials:: [{Cu(2,2′-bpy)-(H2O)}(VO)(O3PCH2PO3)], [Cu(2,2′-bpy)(VO)(O3PCH2CH2PO3)], and [Cu(2,2′-bpy)(VO)(O3PCH2CH2CH2PO3)]•H2O.: Bimetallic phosphonate networks with surface-modifying organic subunits

被引:50
作者
Finn, RC [1 ]
Zubieta, J [1 ]
机构
[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 12期
关键词
D O I
10.1039/b000667j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Hydrothermal reactions of Cu2O or CuCl2 with Na3VO4, 2,2'-bipyridine and the appropriate organodiphosphonate yielded the bimetallic, two-dimensional phosphonate phases, [{Cu(2,2'-bpy)(H2O)}(VO)(O3PCH2PO3)], [Cu(2,2'-bpy)(VO)(O3PCH2CH2PO3)] and [Cu(2,2'-bpy)(VO)(O3PCH2CH2CH2PO3)]. H2O.
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页码:1821 / 1823
页数:3
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