Nonadiabatic calculations of the oscillator strengths for the helium atom in the hyperspherical adiabatic approach

被引:15
作者
Masili, M [1 ]
De Groote, JJ
Hornos, JE
机构
[1] Univ Nebraska, Dept Phys & Astron, Brace Lab 116, Lincoln, NE 68588 USA
[2] Univ Estadual Paulista, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
[3] Univ Sao Paulo, Inst Fis Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
关键词
D O I
10.1088/0953-4075/33/14/303
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Energies and wavefunctions are calculated for the bound states of the helium atom in the hyperspherical adiabatic approach by the full inclusion of nonadiabatic couplings. We show that the use of appropriate asymptotic radial boundary conditions not only allows the efficient calculation of energies accurate up to a few ppm for the ground state but also gives increasingly precise results for high-lying excited states with a unique set of equations. The accuracy of the wavefunctions is demonstrated by the calculation of oscillator strengths in the length form for transitions between stares ii S-1(e) and (n + 1) P-1(0) up to n = 29, in agreement with variational calculations.
引用
收藏
页码:2641 / 2652
页数:12
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