Polymerization of isoprene by a single component lanthanide catalyst precursor

被引：37

作者：

Evans, WJ ^{[1
]}

Giarikos, DG ^{[1
]}

Allen, NT ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

MACROMOLECULES | 2003年 / 36卷 / 12期

关键词：

D O I：

10.1021/ma034385s

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Using a simple single component lanthanide initiator, cis-1,4-polyisoprene was prepared. This was achieved by the discovery of the first molecular complexes of Tm(II), Dy(II), and Nd(II). No evidence of a trans polymer was observed.

引用

页码：4256 / 4257

页数：2

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