Trichlorosilane-dimethylformamide (Cl3SiH-DMF) as an efficient reducing agent. Reduction of aldehydes and imines and reductive amination of aldehydes under mild conditions using hypervalent hydridosilicates

被引：163

作者：

Kobayashi, S

Yasuda, M

Hachiya, I

机构：

[1] Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Tokyo 162, Kagurazaka, Shinjuku-ku

来源：

CHEMISTRY LETTERS | 1996年 / 05期

关键词：

D O I：

10.1246/cl.1996.407

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trichlorosilane-dimethylformamide (Cl3SiH-DMF) was found to be an effective reducing agent for reduction of aldehydes to alcohols, imines to amines, and also reductive amination of aldehydes. Hypervalent silicates are active species, which enable efficient reduction under mild conditions.

引用

页码：407 / 408

页数：2

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