Zinc oxide in cement clinkering:: part 1.: Systems CaO-ZnO-Al2O3 and CaO-ZnO-Fe2O3

被引:43
作者
Bolio-Arceo, H [1 ]
Glasser, FP
机构
[1] Cemex, Div Technol, Monterrey, Mexico
[2] Univ Aberdeen, Dept Chem, Old Aberdeen AB24 3UE, Scotland
关键词
D O I
10.1680/adcr.1998.10.1.25
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The systems CaO-ZnO-Al2O3 (C-Z-A) and CaO-ZnO-Fe2O3 (C-Z-F) have been studied and their phase relationships established. Two hitherfo unreported phases, Ca3ZnAl4O10 (C(3)ZA(2)) and Ca6Zn3Al4O15 (C(6)Z(3)A(2)) were characterized in the system C-Z-A: their X ray diffraction patterns were obtained and indexed No new phases were discovered in the system C-Z-F. Phase coexistence has been established in both systems. C(6)Z(3)A(2) is of particular interest to clinkering because it coexists with alite, belite and a clinker liquid phase. This is confirmed both by laboratory experiment and its identification in white and grey clinkers, made from industrial raw meals doped with 10 and 20 wt% of zinc oxide.
引用
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页码:25 / 32
页数:8
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