Hydrolytic decomposition of dichlorodifluoromethane on modified zirconium oxide surfaces

被引：10

作者：

Hess, A ^{[1
]}

Kemnitz, E ^{[1
]}

机构：

[1] Humboldt Univ, Inst Chem, D-10115 Berlin, Germany

来源：

CATALYSIS LETTERS | 1997年 / 49卷 / 3-4期

关键词：

decomposition; hydrolysis; heterogeneous catalysis; dichlorodifluoromethane; CFC-12; zirconia;

D O I：

10.1023/A:1019001220755

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrolytic decomposition of dichlorodifluoromethane (CFC-12) on various modified zirconium oxide surfaces has been studied. The reaction was carried out under flow conditions at 500 degrees C. Complete CFC-12 conversion and long-time stability of the catalysts were achieved accompanied by a limitation of the undesired CFC-13 formation. A maximum CFC-12 conversion was observed on catalysts of sulfated zirconia or zirconia obtained from temperature-controlled calcination of zirconium oxide hydrate. The reaction depends on the presence or in situ formation of Bronsted acid sites. FTIR-photoacoustic measurements were performed on pyridine complexes chemisorbed on the catalyst surface in order to analyze the changes in the catalyst's acidity. The effects of the temperature and water in the reaction gas on the catalyzed decomposition of CFC-12 are examined.

引用

页码：199 / 205

页数：7

共 10 条

[1] Surface acidity and catalytic behavior of modified zirconium and titanium dioxides [J].