Effect of internal pressure on charge-ordered rare earth manganates

被引:31
作者
Rao, CNR [1 ]
Santhosh, PN
Singh, RS
Arulraj, A
机构
[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[2] Indian Inst Sci, CSIR, Ctr Excellence Chem, Bangalore 560012, Karnataka, India
[3] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
关键词
D O I
10.1006/jssc.1997.7734
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The effect of internal pressure on charge-ordered rare earth manganates of the composition Ln(1-x)A(x)MnO(3) (Ln = La, Pr, Nd and A = Ca, Sr) has been studied by varying the average radius of the A site cations ([r(A)]). Increasing [r(A)] is generally accompanied by an increase in the ferromagnetic transition temperature and a decrease in the charge-ordering transition temperature. On increasing the size of the A site cations by appropriate substitution, charge-ordered insulators such as Pr0.7Ca0.3MnO3 and Nd0.5Ca0.5MnO3 become ferromagnetic, accompanied by an insulator-metal transition. In Pr0.5Sr0.5MnO3, substitution of La in place of Pr destroys the antiferromagnetic transition and favors the ferromagnetic metallic state. (C) 1998 Academic Press.
引用
收藏
页码:169 / 173
页数:5
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