Donorstabilized Aluminium(I) iodide

被引：40

作者：

Ecker, A

Schnockel, H

机构：

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1996年 / 622卷 / 01期

关键词：

A1(I)I; Al-Al bonds; Al-27 NMR spectroscopy; X-ray structure determination;

D O I：

10.1002/zaac.19966220120

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A metastable solution of Al-1-iodide is formed by quenching of gaseous Al-1-iodide, formed from Al-(l) and HI(g) at about 1000 degrees C with a mixture of toluene/diethylether. Using triethylamine as donor and solvent crystalline (AII . NEt(3))(4) 1 can be isolated: a planar Al-4 ring with an Al-Al distance of 265 pm is the most important structural feature in this first roomtemperature stable Al-1-Iodide.

引用

页码：149 / 152

页数：4

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