Determination of the structure and stability of water clusters using temperature dependent techniques

被引:18
作者
Quintana, IM [1 ]
Ortiz, W [1 ]
Lopez, GE [1 ]
机构
[1] Univ Puerto Rico, Dept Chem, Mayaguez, PR 00681 USA
关键词
D O I
10.1016/S0009-2614(98)00167-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The lowest energy equilibrium structure of various water clusters, (H2O)(n), where n = 2-9, was determined using simulated annealing techniques. The interparticle potential was represented by the TIP4P potential and the thermodynamic stability of the systems was computed using a method based on re-scaling the interparticle potential in order to solve the appropriate equations. The structures obtained are similar to the ones reported by other researchers using first principle techniques. All the systems considered are thermodynamically stable in a temperature range when the cluster is in a solid-like form. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:429 / 434
页数:6
相关论文
共 15 条
[1]   Quantifying hydrogen bond cooperativity in water: VRT spectroscopy of the water tetramer [J].
Cruzan, JD ;
Braly, LB ;
Liu, K ;
Brown, MG ;
Loeser, JG ;
Saykally, RJ .
SCIENCE, 1996, 271 (5245) :59-62
[2]  
FREEMAN DL, 1988, ADV CHEM PHYS B, V70, P139
[3]   TEMPERATURE AND SIZE DEPENDENCE FOR MONTE-CARLO SIMULATIONS OF TIP4P WATER [J].
JORGENSEN, WL ;
MADURA, JD .
MOLECULAR PHYSICS, 1985, 56 (06) :1381-1392
[4]   CHEMICAL BONDING IN WATER CLUSTERS [J].
LEE, CT ;
CHEN, H ;
FITZGERALD, G .
JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (03) :1266-1269
[5]   Water clusters [J].
Liu, K ;
Cruzan, JD ;
Saykally, RJ .
SCIENCE, 1996, 271 (5251) :929-933
[6]   MANY-BODY EFFECTS IN MOLECULAR-DYNAMICS SIMULATIONS OF NA+(H2O)N AND CL-(H2O)N CLUSTERS [J].
PERERA, L ;
BERKOWITZ, ML .
JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (03) :1954-1963
[7]   MEASUREMENT OF QUANTUM TUNNELING BETWEEN CHIRAL ISOMERS OF THE CYCLIC WATER TRIMER [J].
PUGLIANO, N ;
SAYKALLY, RJ .
SCIENCE, 1992, 257 (5078) :1937-1940
[8]   Structure and thermodynamics of molecular nitrogen clusters [J].
Rodriguez, I ;
Acevedo, AJ ;
Lopez, GE .
MOLECULAR PHYSICS, 1997, 90 (06) :943-949
[9]   MONTE-CARLO SIMULATION OF (H2O)8 - EVIDENCE FOR A LOW-ENERGY S4 STRUCTURE AND CHARACTERIZATION OF THE SOLID REVERSIBLE LIQUID TRANSITION [J].
TSAI, CJ ;
JORDAN, KD .
JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (05) :3850-3853
[10]   USE OF THE HISTOGRAM AND JUMP-WALKING METHODS FOR OVERCOMING SLOW BARRIER CROSSING BEHAVIOR IN MONTE-CARLO SIMULATIONS - APPLICATIONS TO THE PHASE-TRANSITIONS IN THE (AR)13 AND (H2O)8 CLUSTERS [J].
TSAI, CJ ;
JORDAN, KD .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (09) :6957-6970