Simple linear-chain cobalt phosphates

被引：29

作者：

Choudhury, A

Natarajan, S

Rao, CNR

机构：

[1] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b002653k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two simple one-dimensional cobalt phosphates containing linear chains of corner-shared 4-membered rings have been synthesized hydrothermally by the reaction between amine phosphates and cobalt(II) ions under non-aqueous conditions. The linear chains are held together by hydrogen bond interactions involving the hydrogens of the amine and the framework oxygens. The two cobalt phosphates reported are the first linear chain compounds discovered in the family of open-framework transition metal phosphates.

引用

页码：2595 / 2598

页数：4

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