Transition-metal complexes with sterically demanding ligands:: Facile thermal intermolecular C-H bond activation in a square-planar IrI complex, Part 4.

被引：21

作者：

Nückel, S ^{[1
]}

Burger, P ^{[1
]}

机构：

[1] Univ Zurich, Inst Anorgan Chem, CH-8057 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 14期

关键词：

C-H bond activation; density functional theory; iridium; N ligands;

D O I：

10.1002/anie.200219908

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Teaching an old dog a new trick: A novel square-planar iridium(I) system undergoes facile thermal intermolecular C-H activation process at ambient temperature (see scheme). The observed unusual low activation barrier is analyzed and traced by DFT methods which provide guidelines for the design of novel systems, which would allow the activation of methane under mild conditions.

引用

页码：1632 / 1636

页数：5

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