Photoreductive coupling of aldimines, synthesis of C2 symmetrical diamines

被引：20

作者：

Campos, PJ ^{[1
]}

Arranz, J ^{[1
]}

Rodríguez, MA ^{[1
]}

机构：

[1] Univ La Rioja, Grp Sintesis Quim, CSIC, Dept Quim,Unidad Asociada, Logrono 26071, Spain

来源：

TETRAHEDRON | 2000年 / 56卷 / 37期

关键词：

imines; photoreductive coupling; diamines;

D O I：

10.1016/S0040-4020(00)00625-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photoreductive coupling of pyridine-, arene- and alkynecarboxaldimines is a very convenient procedure for the preparation of vicinal diamines in good to excellent yields. The usual trend gave an excess of meso diamine, which enhances the usefulness of this method. The procedure tolerates bulky groups such as tert-butyl and diphenylmethyl on the nitrogen atom. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：7285 / 7289

页数：5

共 16 条

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