Pulsed electrodeposition of WO3-TiO2 composite films

被引:91
作者
de Tacconi, NR [1 ]
Chenthamarakshan, CR
Rajeshwar, K
Pauporté, T
Lincot, D
机构
[1] Univ Texas, Dept Biochem & Chem, Arlington, TX 76019 USA
[2] Ecole Natl Super Chim, UMR CNRS 7575, Lab Electrochim & Chim Analyt, F-75231 Paris 05, France
关键词
ultraviolet irradiation; thermal anneal; photoaction spectra; photoelectrochemical behavior;
D O I
10.1016/S1388-2481(03)00021-3
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Cathodic electrodeposition was used to prepare thin films of WO3 and TiO2 on F-doped SnO2 glass substrates. A new pulsed deposition technique was developed to prepare WO3-TiO2 composite films over a wide compositional range. Such composite films containing comparable amounts of WO3 and TiO2 showed superior photoelectrochemical performance in 0.1 M Na2SO4 relative to the component oxides themselves. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:220 / 224
页数:5
相关论文
共 28 条
  • [1] Novel electrochromic devices based on complementary nanocrystalline TiO2 and WO3 thin films
    Bonhôte, P
    Gogniat, E
    Grätzel, M
    Ashrit, PV
    [J]. THIN SOLID FILMS, 1999, 350 (1-2) : 269 - 275
  • [2] Pulsed plasma polymerization of tetramethyltin: Nanoscale compositional control of film chemistry
    Chen, XL
    Rajeshwar, K
    Timmons, RB
    Chen, JJ
    Chyan, OMR
    [J]. CHEMISTRY OF MATERIALS, 1996, 8 (05) : 1067 - 1077
  • [3] Structure of WOx/TiO2 catalysts prepared from hydrous titanium oxide hydroxide:: Influence of preparation parameters
    Eibl, S
    Gates, BC
    Knözinger, H
    [J]. LANGMUIR, 2001, 17 (01) : 107 - 115
  • [4] LIFETIME OF ELECTROCHROMISM OF AMORPHOUS WO3-TIO2 THIN-FILMS
    HASHIMOTO, S
    MATSUOKA, H
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (08) : 2403 - 2408
  • [5] Comparison of photoelectrochromic devices with different layer configurations
    Hauch, A
    Georg, A
    Krasovec, UO
    Orel, B
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (09) : H159 - H163
  • [6] Photovoltaically self-charging battery
    Hauch, A
    Georg, A
    Krasovec, UO
    Orel, B
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (09) : A1208 - A1211
  • [7] New photoelectrochromic device
    Hauch, A
    Georg, A
    Baumgärtner, S
    Krasovec, UO
    Orel, B
    [J]. ELECTROCHIMICA ACTA, 2001, 46 (13-14) : 2131 - 2136
  • [8] HONGO K, UNPUB J ELECTROANAL
  • [9] Enhanced photocurrent-voltage characteristics of Ru(II)-dye sensitized TiO2 solar cells with TiO2-WO3 buffer layers prepared by a sol-gel method
    Kang, TS
    Moon, SH
    Kim, KJ
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (05) : E155 - E158
  • [10] PREPARATION OF TIO2 (ANATASE) FILMS ON ELECTRODES BY ANODIC OXIDATIVE HYDROLYSIS OF TICL3
    KAVAN, L
    OREGAN, B
    KAY, A
    GRATZEL, M
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 346 (1-2): : 291 - 307