Photochromic radical compounds based on a naphthopyran system

被引:24
作者
Kaneko, T [1 ]
Akutsu, H [1 ]
Yamada, J [1 ]
Nakatsuji, S [1 ]
机构
[1] Himeji Inst Technol, Grad Sch Sci, Dept Mat Sci, Kamigori, Hyogo 6781297, Japan
关键词
D O I
10.1021/ol034574v
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Naphthopyran derivatives with aminoxyl substituents (4a,b) gave the corresponding open-formed isomers (5a,b) by irradiation, which could be changed back to the starting closed-formed naphthopyrans by the treatment with SiO2 as a catalyst. The tuning of intermolecular magnetic interactions between the isomer couples was found to be possible in these reversible systems.
引用
收藏
页码:2127 / 2129
页数:3
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