Partial oxidation of alcohols in supercritical carbon dioxide

被引：66

作者：

Jenzer, G ^{[1
]}

Sueur, D ^{[1
]}

Mallat, T ^{[1
]}

Baiker, A ^{[1
]}

机构：

[1] ETH Zentrum, Swiss Fed Inst Technol, Tech Chem Lab, CH-8092 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b007114p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of water-insoluble alcohols in supercritical CO2 over a Pd-Pt-Bi/C catalyst in a continuous fixed bed reactor affords high reaction rates and yields up to 98% of the corresponding ketones, aromatic and alpha,beta -unsaturated aliphatic aldehydes, without the risk of using a flammable organic solvent.

引用

页码：2247 / 2248

页数：2

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