Synthesis and properties of bis(ethyleneseleno)tetrathiafulvalene (BES-TTF) and diselenolotetrathiafulvalene (DS-TTF) as novel electron donors

被引:13
作者
Jigami, T [1 ]
Takimiya, K [1 ]
Aso, Y [1 ]
Otsubo, T [1 ]
机构
[1] HIROSHIMA UNIV, FAC ENGN, DEPT APPL CHEM, HIGASHIHIROSHIMA 739, JAPAN
关键词
D O I
10.1246/cl.1997.1091
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title selenocycle-fused tetrathiafulvalene derivatives, BES-TTF and DS-TTF have been synthesized as novel electron donors, and their conductive charge-transfer complexes have been studied. All complexes of the BES-TTF compound with TCNQ, ClO4, and PF6 showed very high conductivities of the order of 10(2) S.cm(-1) as well as metallic temperature-dependent behavior.
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收藏
页码:1091 / 1092
页数:2
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