Metal segregation in bimetallic clusters and its possible role in synergism and bifunctional catalysis

被引：61

作者：

Adams, RD ^{[1
]}

机构：

[1] Univ S Carolina, Phys Sci Ctr, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 600卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

catalysis; bimetallic; mixed-metal; synergism; platinum; ruthenium;

D O I：

10.1016/S0022-328X(00)00028-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aspects of the reactivity of segregated bimetallic compounds and their unusual catalytic properties are reviewed with an emphasis on the author's own studies of platinum-ruthenium mixed-metal cluster complexes and their ability to produce hydrogenation and hydrosilylation of alkynes, catalytically. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：1 / 6

页数：6

共 100 条

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[8] CLUSTER SYNTHESIS .39. NEW PLATINUM RUTHENIUM CARBONYL CLUSTER COMPLEXES WITH BRIDGING HYDRIDE LIGANDS - SYNTHESIS AND STRUCTURAL CHARACTERIZATIONS OF RU4PT(CO)13(COD)(MU-H)2, RU3PT(CO)9(MU-CO)(COD)(MU-H)2, RU4PT2(CO)11(COD)2(MU-3-H)2, AND RU5PT5(CO)18(COD)2(MU-H)2, COD = CYCLOOCTA-1,5-DIENE [J].

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