Generation of an unprecedented excited state oxidant in a coordinately unsaturated platinum complex

被引：57

作者：

Base, K ^{[1
]}

Grinstaff, MW ^{[1
]}

机构：

[1] Duke Univ, Paul M Gross Chem Lab, Dept Chem, Durham, NC 27708 USA

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 07期

关键词：

D O I：

10.1021/ic971400z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new diimine dithiolate-ortho-carborane platinum(II) complexes have been synthesized and characterized. These platinum chromophores are photochemically stable, soluble in solvents of varying polarities, and potent oxidizing agents in their excited state. [GRAPHICS] (OMe)(12)(dbm)(6)](+), whereas the iron(III) analogue has S = 0. [GRAPHICS]

引用

页码：1432 / +

页数：3

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