A key intermediate in the platinum-mediated hydrodesulfurization of dibenzothiophene

被引：11

作者：

Iretskii, A

Garcia, JJ

Picazo, G

Maitlis, PM ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

[2] Univ Nacl Autonoma Mexico, Fac Quim, Mexico City 04510, DF, Mexico

来源：

CATALYSIS LETTERS | 1998年 / 51卷 / 1-2期

关键词：

hydrodesulfurization; dibenzothiophene; platinum;

D O I：

10.1023/A:1019053521605

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thiaplatinacycles, [PtL2(C,S-C12H8S)] and [PtL2(C,S-C13H1OS)] (L = PEt3, PMe3; L-2 = Ph2PCH2CH2PPh2), obtained from oxidative insertion of [(PtLn)-L-0] into dibenzothiophene and 4-methyldibenzothiophene are hydrodesulfurized by reaction with hydrogen (toluene, 20 atm, 100 degrees C) to biphenyl and 3-methylbiphenyl, respectively; addition of acidic alumina improves the reaction. These observations link the model systems and the latest generation of commercial second-stage HDS catalysts.

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页码：129 / 131

页数：3

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