Agostic interactions in transition metal compounds

被引：941

作者：

Brookhart, Maurice ^{[1
]}

Green, Malcolm L. H.

Parkin, Gerard

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

[2] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[3] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2007年 / 104卷 / 17期

关键词：

D O I：

10.1073/pnas.0610747104

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The impact of agostic interactions (i.e., 3-center-2-electron M-H-C bonds) on the structures and reactivity of organotransition metal compounds is reviewed.

引用

页码：6908 / 6914

页数：7

共 89 条

[1] PLATINUM INDUCED C-H ACTIVATION IN AROMATIC-ALDEHYDES - UNUSUAL J(PT,H) COUPLING-CONSTANTS AND STRUCTURE OF TRANS-DICHLOROQUINOLINE-8-CARBOXALDEHYDE TRIETHYLPHOSPHINE PLATINUM(II) [J].

ALBINATI, A ;

ANKLIN, CG ;

PREGOSIN, PS .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 90 (03) :L37-L38

[2] PREPARATIVE AND H-1-NMR SPECTROSCOPIC STUDIES ON PALLADIUM(II) AND PLATINUM(II) QUINOLINE-8-CARBALDEHYDE (1) COMPLEXES - X-RAY STRUCTURES OF THE CYCLOMETALATED ACYL COMPLEX PDCL(C(O)C9H6N)(PPH3).PPH3 AND TRANS-PTCL2(1)(PET3) [J].

ALBINATI, A ;

ANKLIN, CG ;

GANAZZOLI, F ;

RUEGG, H ;

PREGOSIN, PS .

INORGANIC CHEMISTRY, 1987, 26 (04) :503-508

[3] WEAK PT-H-C INTERACTIONS - EXTENSIONS TO 8-METHYLQUINOLINE, BENZOQUINOLINE, AND A TETRALONE SCHIFF-BASE - X-RAY CRYSTAL-STRUCTURE OF TRANS-PTCL2(BENZOQUINOLINE)(PET3) [J].

ALBINATI, A ;

PREGOSIN, PS ;

WOMBACHER, F .

INORGANIC CHEMISTRY, 1990, 29 (10) :1812-1817

[4] NJ(PT,H) AND PT-LESS-THAN-H-C INTERACTIONS IN SCHIFF-BASE COMPLEXES OF 2-(BENZYLIDENEAMINO)-3-METHYLPYRIDINE - MOLECULAR-STRUCTURES OF DICHLORO(2-((2,4,6-TRIMETHYLBENZYLIDENE)AMINO)-3-METHYLPYRIDINE)(TRIETHYLARSINE)PLATINUM(II) AND DICHLORO(2-AMINO-3-METHYLPYRIDINE)(TRIETHYLPHOSPHINE)PALLADIUM(II) [J].

ALBINATI, A ;

ARZ, C ;

PREGOSIN, PS .

INORGANIC CHEMISTRY, 1987, 26 (04) :508-513

[5] ZIEGLER-NATTA CATALYSIS .3. STEREOSPECIFIC POLYMERIZATION OF PROPENE WITH THE CATALYST SYSTEM TICL3-ALET3 [J].

ARLMAN, EJ ;

COSSEE, P .

JOURNAL OF CATALYSIS, 1964, 3 (01) :99-104

[6] A NEW MECHANISM FOR EXCHANGE PROCESSES OBSERVED IN THE COMPOUNDS [NB(ETA-C5H5)2(EXO-ETA-RCH=CH2)H], [TA(ETA-C5H5)2(EXO-ETA-RCH=CH2)H] [J].

BERCAW, JE ;

BURGER, BJ ;

GREEN, MLH ;

SANTARSIERO, BD ;

SELLA, A ;

TRIMMER, MS ;

WONG, LL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (11) :734-736

[7] SYNTHESIS AND 2D NMR-STUDIES OF (BIS(PYRAZOLYL)BORATO)RHODIUM(I) COMPLEXES WITH WEAK RH...H...C INTERACTIONS AND THE X-RAY CRYSTAL-STRUCTURE OF ((CYCLOOCTANE-1,5-DIYL)BIS(PYRAZOL-1-YL)BORATO)(1,5-CYCLOOCTADIENE)RHODIUM [J].

BORTOLIN, M ;

BUCHER, UE ;

RUEGGER, H ;

VENANZI, LM ;

ALBINATI, A ;

LIANZA, F ;

TROFIMENKO, S .

ORGANOMETALLICS, 1992, 11 (07) :2514-2521

[8] Agostic interactions in organometallic compounds. A Cambridge Structural Database study [J].

Braga, D ;

Grepioni, F ;

Biradha, K ;

Desiraju, GR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (20) :3925-3930

[9] Hydrogen bonding in organometallic crystals .6. X-H---M hydrogen bonds and M---(H-X) pseudo-agostic bonds [J].

Braga, D ;

Grepioni, F ;

Tedesco, E ;

Biradha, K ;

Desiraju, GR .

ORGANOMETALLICS, 1997, 16 (09) :1846-1856

[10] THE ROLE OF TRANSITION-METAL ATOMS AS HYDROGEN-BOND ACCEPTORS - A NEUTRON-DIFFRACTION STUDY OF [NPRN4]2[PTCL4].CIS-[PTCL2(NH2ME)2] AT 20-K [J].

BRAMMER, L ;

CHARNOCK, JM ;

GOGGIN, PL ;

GOODFELLOW, RJ ;

ORPEN, AG ;

KOETZLE, TF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07) :1789-1798

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