From nanocomposite to nanogel polymer electrolytes

被引:126
作者
Jacob, MME [1 ]
Hackett, E [1 ]
Giannelis, EP [1 ]
机构
[1] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
关键词
D O I
10.1039/b204458g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This review discusses recent advances in polymer electrolyte nanocomposites. In particular, we highlight our recent understanding on the structure and dynamics at the polymer/nanoparticle interface and attempt to correlate to macroscopic properties. We also discuss our current effort on nanogel electrolytes synthesized by incorporating layered nanoparticles into a gel. The nanogel electrolytes combine the high ambient conductivity of conventional gel electrolytes with the excellent stability toward the metal electrode and the good mechanical properties of nanocomposite electrolytes.
引用
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页码:1 / 5
页数:5
相关论文
共 44 条
[1]   Nanoscopic-confinement effects on local dynamics [J].
Anastasiadis, SH ;
Karatasos, K ;
Vlachos, G ;
Manias, E ;
Giannelis, EP .
PHYSICAL REVIEW LETTERS, 2000, 84 (05) :915-918
[2]   Variations on the salt-polymer electrolyte theme for flexible solid electrolytes [J].
Angell, CA ;
Xu, K ;
Zhang, SS ;
Videa, M .
SOLID STATE IONICS, 1996, 86-8 :17-28
[3]   RUBBERY SOLID ELECTROLYTES WITH DOMINANT CATIONIC TRANSPORT AND HIGH AMBIENT CONDUCTIVITY [J].
ANGELL, CA ;
LIU, C ;
SANCHEZ, E .
NATURE, 1993, 362 (6416) :137-139
[4]  
[Anonymous], 1997, CHIM IND-MILAN
[5]  
[Anonymous], 1994, LITHIUM BATTERIES NE
[6]   High-performance electrolyte membranes for plastic lithium batteries [J].
Appetecchi, GB ;
Croce, F ;
Scrosati, B .
JOURNAL OF POWER SOURCES, 1997, 66 (1-2) :77-82
[7]   POLY(ETHYLENE OXIDE)-SILICATE INTERCALATION MATERIALS [J].
ARANDA, P ;
RUIZHITZKY, E .
CHEMISTRY OF MATERIALS, 1992, 4 (06) :1395-1403
[8]   IONIC-CONDUCTIVITY IN LAYER SILICATES CONTROLLED BY INTERCALATION OF MACROCYCLIC AND POLYMERIC OXYETHYLENE COMPOUNDS [J].
ARANDA, P ;
GALVAN, JC ;
CASAL, B ;
RUIZHITZKY, E .
ELECTROCHIMICA ACTA, 1992, 37 (09) :1573-1577
[9]   POLYMERS WITH IONIC-CONDUCTIVITY [J].
ARMAND, M .
ADVANCED MATERIALS, 1990, 2 (6-7) :278-286
[10]  
Armand M. B., 1979, Fast Ion Transport in Solids. Electrodes and Electrolytes, P131